Caroline married Carl Friedrick Valentiner 7 Apr 1823, Harzgerode, Prussia, Germany. Carl (son of Friedrich Valentiner and Dorothea Janecke) was born 19 May 1793, Kiel, Germany; died Yes, date unknown. [Group Sheet]

1. Carl Heinrich Valentiner was born 20 Aug 1824, of Harzgerode, Prussia, Germany; died Yes, date unknown.
2. Ernst Wilhelm Valentiner was born 8 Feb 1826, of Harzgerode, Prussia, Germany; died 15 Aug 1839, of Harzgerode, Prussia, Germany.
3. Reinhold Friedrich Valentiner was born 16 Jun 1827, of Harzgerode, Prussia, Germany; died Yes, date unknown.
4. Emilie Friederike Luise Valentiner was born 24 Feb 1829, of Harzgerode, Prussia, Germany; died Yes, date unknown.